Maro Publications

Polyolefin Copolymers

Notes

*3/20/2013 
from 3/20/2013

Maro Encyclopedia

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Polyolefins

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Notes

A more specific type of olefin is a poly-alpha-olefin (or poly-α-olefin, sometimes abbreviated as PAO), a polymer made by polymerizing an alpha-olefin. An alpha-olefin (or α-olefin) is an alkene where the carbon-carbon double bond starts at the α-carbon atom, i.e. the double bond is between the #1 and #2 carbons in the molecule. Common alpha-olefins used as co-monomers to give a polymer alkyl branching groups are similar to 1-hexene or may be longer

Many poly-alpha-olefins have flexible alkyl branching groups on every other carbon of their polymer backbone chain. These alkyl groups, which can shape themselves in numerous conformations, make it very difficult for the polymer molecules to line themselves up side-by-side in an orderly way. Therefore, many poly-alpha-olefins do not crystallize or solidify easily and are able to remain oily, viscous liquids even at lower temperatures. Low molecular weight poly-alpha-olefins are useful as synthetic lubricants such as synthetic motor oils for vehicles used in a wide temperature range.

Even polyethylenes copolymerized with a small amount of alpha-olefins (such as 1-hexene, 1-octene, or longer) are more flexible than simple straight chain high density polyethylene, which has no branching. The methyl branch groups on a polypropylene polymer are not long enough to make typical commercial polypropylene more flexible than polyethylene.

(Polyolefins. Wikipedia, 3/20/2013)

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Interested!!
Bookmark this page to follow future developments!.
(RDC 6/5/2012)

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Roger D. Corneliussen
Editor
www.maropolymeronline.com

Maro Polymer Links
Tel: 610 363 9920
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E-Mail: cornelrd@bee.net  

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Copyright 2013 by Roger D. Corneliussen.
No part of this transmission is to be duplicated in any manner or forwarded by electronic mail without the express written permission of Roger D. Corneliussen
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* Date of latest addition; date of first entry is 3/20/2013.